Novel stereospecific synthesis of 3-chloroacrylate esters via palladium- catalyzed carbonylation of terminal acetylenes

DOI: 10.1021/jo982345u

Source and publish data:

Journal of Organic Chemistry p. 5984 - 5987 (1999)

Update date:2022-08-04

Topics:

Authors:

Li, Jinheng

Jiang, Huanfeng

Feng, Aiqun

Jia, Lanqi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo982345u

A simple and effective method for the highly regio- and stereospecific synthesis of (Z)-3-chloroacrylate esters is described. Using terminal acetylenes and primary, secondary, and tertiary aliphatic alcohols as substrates, the carbonylation reactions were

Full text of DOI:10.1021/jo982345u

Products guided by the article

Product name:methyl (E)-3-chloro-3-phenylprop-2-enoate

Cas No:116373-35-4

R&D Labs maybe for 116373-35-4

Xinchang Yueding Chemical Co., Ltd.

Contact:86-571-56926323

Address:NO.90 BEIMENCHENGWAI CHENGGUAN TOWN XINCHANG
Taizhou Sunny Chemical Co.,Ltd

Contact:+86-523-86920899 +86-13951172783

Address:No.11 Xingyuang road, Gaoyong Chemical Industry Park, Gaogang Jiangsu China
SHUNYUANSHENG BIO-PHARMTECH CO., LTD

website:https://www.whsysbio.com

Contact:--

Address:Building 13, Liandong U Valley-Wuhan Economic Innovation Valley, No. 259, Xingsan Road, Shamao Street, Hannan District, Wuhan City, Hubei Province
Zibo Jujin Chemical Industry Co., Ltd.（Dongming Jujin Chemical Industry Co., Ltd. ）

Contact:+86-533-2975022

Address:No.99 Shanquan Road, Zhangdian District
WEIFANG DERUN CHEMICAL CO.,LTD

Contact:86-536-8956886

Address:weifang

Relevant to this article

Study on disulfur-backboned nucleic acid: Part 1, efficient synthesis of 3′,5′-dithio-2′-deoxyadenosine

Doi:10.1055/s-2004-834809
(2004)
A new method for regioselective introduction of trifluoromethyl groups into heteroarenes; Part 2. Nucleophilic substitution of 5-fluoro-4-trifluoromethyl-1,3-azoles

Doi:10.1055/s-1988-27510
(1988)
Reactivity of UI₄(OEt₂)₂ with phenols: Probing the chemistry of the U-I bond

Doi:10.1039/b823002a
(2009)
Studies toward the duocarmycin prodrugs for the antibody prodrug therapy approach

Doi:10.1016/j.tetlet.2009.03.205
(2009)
CuBr-mediated oxyalkylation of vinylarenes under aerobic conditions via cleavage of sp³ C-H bonds α to oxygen

Doi:10.1021/ol900947d
(2009)
Zn(OAc)₂-catalyzing ring-opening polymerization of N-carboxyanhydrides for the synthesis of well-defined polypeptides

Doi:10.3390/molecules23040760
(2018)

Article Doi