Reaction of Tin Enolates with Substituted Tricarbonylcyclohexadienyliumiron Hexafluorophosphate Electrophiles: Diastereoselective Synthesis of (+/-)-Trichodiene

DOI: 10.1039/c39870001445

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1445 - 1447 (1987)

Update date:2022-07-29

Topics:

Authors:

Pearson, Anthony J.

O'Brien, Michael K.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39870001445

A number of tin enolates react cleanly with tricarbonylcyclohexadienyliumiron cations, in cases where the use of lithium enolates or silyl enol ethers is problematic; this new carbon-carbon bond-forming reaction allows diastereoselective construction of p

Full text of DOI:10.1039/c39870001445

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:1-methyl-1-(1-methyl-2-methylenecyclopentyl)-4-methylene-2-cyclohexene

Cas No:116425-56-0

R&D Labs maybe for 116425-56-0

Shanghai Egoal Chemical Co.,Ltd

Contact:+86-21-50333091

Address:Yangming Garden Square 3,YangGao North Road 1188, Pudong New District, Shanghai
Shanghai Korey Pharm Co.,Ltd.(expird)

Contact:021-61840961 021-61840962

Address:No.157,Zhuguang Rd, Qingpu, Shanghai, China
SuZhou Bichal Biological Technology CO.,LTD

Contact:+86-512-68051130

Address:NO.32 huoju road HI-TECH Industrial development zone SuZhou China
Nanjing Raise Pharmatech Co., Ltd

website:http://www.raisechem.com

Contact:+86-25-58649566

Address:B381,No.606,Ningliu Road,Jiangbei New Area,Nanjing,Jiangsu Province,China
enantiotech corporation ltd

Contact:+86-0760-85282375

Address:zhongjing road,zhongshan torch hi-tech industrial development zone

Relevant to this article

Olefins from biomass feedstocks: Catalytic ester decarbonylation and tandem Heck-type coupling

Doi:10.1039/c4cc09003a
(2015)
Incorporation of 8-histaminyldeoxyadenosine 18-(2-(4-imidazolyl)ethylamino)-2'-deoxyriboadenosine] into oligodeoxyribonucleotides by solid phase phosphoramidite coupling.

Doi:10.1081/NCN-120015723
(2002)
Chiral Cu(II) complexes as recyclable catalysts for asymmetric nitroaldol (Henry) reaction in ionic liquids as greener reaction media

Doi:10.1007/s10562-010-0443-8
(2010)
4-(N,N -dimethylamino)pyridine hydrochloride as a recyclable catalyst for acylation of inert alcohols: Substrate scope and reaction mechanism

Doi:10.1021/ol4030875
(2014)
Co(III) and Fe(III) complexes of Schiff bases derived from 2,4-dihydroxybenzaldehyde S-allyl-isothiosemicarbazonehydrobromide

Doi:10.1080/00958972.2013.856420
(2013)
Phosphines with N-heterocyclic boranyl substituents

Doi:10.1039/c3dt52441h
(2014)

Article Doi