Palladium-mediated silylation of organic halides with disilane/F- reagent

DOI: 10.1016/S0040-4039(00)96607-3

Source and publish data:

Tetrahedron Letters p. 4715 - 4718 (1987)

Update date:2022-08-05

Topics:

Authors:

Hatanaka, Yasou

Hiyama, Tamajiro

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Article abstract of DOI:10.1016/S0040-4039(00)96607-3

Under catalytic influence of tetrakis(triphenylphosphine)palladium, tris(diethylamino)sulfonium trimethyldiflourosilicate promoted the reaction of vynil halides with hexamethyldisilane to give corresponding vinyl silanes in good yields chemoselectivity and stereospecifically.

Full text of DOI:10.1016/S0040-4039(00)96607-3

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