Tetrahedron Letters p. 653 - 654 (1988)
Update date:2022-08-02
Topics:
Toda, Fumio
Tanaka, Koichi
Oda, Masaji
By complexing with the title host compound, flipping equilibrium of cycloocta-2,4,6-trien-1-one was frozen in one optical conformer as a 2:1 complex, which upon irradiation gave optically active bicyclo<4.2.0>octa-4,7-dien-2-one.Irradiation of a 1:2 complex of cycloocta-2,4-dien-1-one and the same host compound gave an optically active dimer, anti-tricyclo<8.6.0.02,9>hexa-deca-7,11-diene-3,16-dione.
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