Cyclopentanoid Synthesis via Directed Cationic Cyclizations. Efficient Generation and Rearrangement of the Intermediate Cyclohexyl Cation

DOI: 10.1021/jo00255a052

Source and publish data:

Journal of Organic Chemistry p. 4894 - 4896 (1988)

Update date:2022-07-29

Topics:

Authors:

Sworin, Michael

Neumann, William L.

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Article abstract of DOI:10.1021/jo00255a052

Acyclic acetals in the presence of SnCl4 initiate a cationic cyclization pathway, which is directed to cyclopentanoid ring formation via pinacol rearrangement step.

Full text of DOI:10.1021/jo00255a052

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