Unusually Ready Cleavage of an S-Cα Bond in Sterically Crowded Sulphoxides

DOI: 10.1039/c39880000040

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 40 - 41 (1988)

Update date:2022-07-29

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Authors:

Okazaki, Renji

Ishida, Takayuki

Inamoto, Naoki

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Article abstract of DOI:10.1039/c39880000040

Oxidation of sterically crowded sulphides containing a 2,4,6-tri-t-butylphenyl group or its Dewar benzene analogue affords unusually unstable sulphoxides which undergo ready heterolytic S-C_α cleavage to give indan derivatives and sulphenic acid

Full text of DOI:10.1039/c39880000040

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