Journal of the Chemical Society. Chemical communications p. 495 - 496 (1988)
Update date:2022-07-29
Topics:
Battye, Peter J.
Jones, David W.
Tucker, Harvey P.
The 7-formylnorcaradiene (1; X=O, R=Me) rearranges at 40 deg C to the dihydrobenzofuran (4; X=O, R=Me) and the 7-vinylnorcaradiene (1, X=E-CHCO2Et, R=Me) rearranges to the dihydroindene (9), evidence for 3,5-rather than 1,3-sigmatropy in both processes.
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