AN EFFICIENT SYNTHETIC METHOD OF METHYL (+/-)-JASMONATE

DOI: 10.1016/S0040-4020(01)83449-9

Source and publish data:

Tetrahedron p. 4107 - 4112 (1987)

Update date:2022-08-04

Topics:

Authors:

Kataoka, Hideaki

Yamada, Toshiro

Goto, Kuniaki

Tsuji, Jiro

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Article abstract of DOI:10.1016/S0040-4020(01)83449-9

An efficient synthetic method of methyl (+/-)-jasmonate is described. 2-Pentynyl-2-cyclopentenone, the key intermediate in this route, was synthesized by applying the palladium-catalyzed enone formation from allyl β-keto carboxylate as a key reaction.

Full text of DOI:10.1016/S0040-4020(01)83449-9

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