Journal of Organic Chemistry p. 5153 - 5162 (1993)
Update date:2022-08-04
Topics:
Bell, Thomas W.
Ciaccio, James A.
The alkylative rearrangement of 1,2-epoxy-3-alkanol tosylates is applied to the synthesis of chiral epoxide pheromones.Attack at the terminal carbon atom of epoxy tosylates by lithioacetylenes and cyclization of the intermediate tosyloxy alcohols produces
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