An asymmetric approach to 5-O-carbamoyl-2-epi-polyoxamic acid and the total synthesis of 2′′-epi-polyoxin J

DOI: 10.1016/j.tetasy.2009.03.033

Source and publish data:

Tetrahedron Asymmetry p. 1174 - 1180 (2009)

Update date:2022-08-05

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Authors:

Luo, Yong-Chun

Zhang, Huan-Huan

Liu, Yao-Zong

Cheng, Rui-Ling

Xu, Peng-Fei

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Article abstract of DOI:10.1016/j.tetasy.2009.03.033

A stereospecific synthetic approach to 5-O-carbamoyl-2-epi-polyoxamic acid has been developed. The asymmetric nucleophilic addition of 2-lithiofuran to a tert-butanesulfinyl imine was employed as the key step to construct the C-2 stereocenter and 2′′-epi-

Full text of DOI:10.1016/j.tetasy.2009.03.033

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