Asymmetric synthesis of 2-alkyl-3-phosphonopropanoic acid derivatives via Rh-catalyzed asymmetric hydrogenation

DOI: 10.1016/j.tetasy.2011.12.002

Source and publish data:

Tetrahedron Asymmetry p. 2117 - 2123 (2011)

Update date:2022-09-26

Topics:

Authors:

Luo, Li-Bin

Wang, Dao-Yong

Zhou, Xiao-Mao

Zheng, Zhuo

Hu, Xiang-Ping

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Article abstract of DOI:10.1016/j.tetasy.2011.12.002

The commercially available ferrocene-based diphosphine ligand (S _c,S_Fc)-TaniaPhos was found to be highly effective in the Rh-catalyzed asymmetric hydrogenation of 3-aryl-2-(phosphonomethyl)propenates. Excellent enantioselectivity (90

Full text of DOI:10.1016/j.tetasy.2011.12.002

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