Journal of the American Chemical Society p. 475 - 477 (1989)
Update date:2022-08-03
Topics:
Hoemberger, Guenter
Dorigo, Andrea E.
Kirmse, Wolfgang
Houk, K. N.
Triplet arylcarbenes react intramolecularly with unsaturated ortho substituents, while singlet arylcarbenes react preferentially with solvent methanol.Rotation about the exocyclic C-CH bond is necessary in order for cycloaddition of the singlet carbene to
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