Rapid Intramolecular Addition Reactions of Triplet Arylcarbenes

DOI: 10.1021/ja00184a011

Source and publish data:

Journal of the American Chemical Society p. 475 - 477 (1989)

Update date:2022-08-03

Topics:

Authors:

Hoemberger, Guenter

Dorigo, Andrea E.

Kirmse, Wolfgang

Houk, K. N.

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Article abstract of DOI:10.1021/ja00184a011

Triplet arylcarbenes react intramolecularly with unsaturated ortho substituents, while singlet arylcarbenes react preferentially with solvent methanol.Rotation about the exocyclic C-CH bond is necessary in order for cycloaddition of the singlet carbene to

Full text of DOI:10.1021/ja00184a011

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