Tetrahedron p. 2583 - 2590 (1988)
Update date:2022-08-04
Topics:
Chambers, Richard D.
Shepherd, Thomas
Masayuki, Tamura
Reaction of trichloro-1,2,3-triazine (1) with potassium fluoride at elevated temperatures gives trifluoro-1,2,3-triazine (4) and corresponding chlorofluoro derivatives.Introduction of perfluoroisopropyl groups occurs, using fluoride ion and hexafluoropropene.A novel product (7) is described that arises from nucleophilic attack of perfluoroisopropyl anion on ring nitrogen in an intermediate triazine derivative.
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