THE 1,4 O->C SILYL MIGRATIONS OF VARIOUS 3--FURANS AND -THIOPHENES

DOI: 10.1016/S0040-4039(00)96838-2

Source and publish data:

Tetrahedron Letters p. 5965 - 5968 (1987)

Update date:2022-09-26

Topics: Product Formation Starting Materials

Authors:

Bures, Edward J.

Keay, Brian A.

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Article abstract of DOI:10.1016/S0040-4039(00)96838-2

Numerous 3-<(trialkylsilyl)oxymethyl>-furans and -thiophenes undergo a 1,4 O->C silyl migration when treated with n-BuLi/HMPA in THF or DME to produce 2-(trialkylsilyl)-3-(hydroxymethyl)-furans and -thiophenes in good yields.

Full text of DOI:10.1016/S0040-4039(00)96838-2

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Product name:[2-(Dimethyl-phenyl-silanyl)-furan-3-yl]-methanol

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