Tetrahedron Letters p. 5965 - 5968 (1987)
Update date:2022-09-26
Topics: Product Formation Starting Materials
Bures, Edward J.
Keay, Brian A.
Numerous 3-<(trialkylsilyl)oxymethyl>-furans and -thiophenes undergo a 1,4 O->C silyl migration when treated with n-BuLi/HMPA in THF or DME to produce 2-(trialkylsilyl)-3-(hydroxymethyl)-furans and -thiophenes in good yields.
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Doi:10.1002/jccs.200800197
(2008)Doi:10.1021/om900231c
(2009)Doi:10.1021/jm900622d
(2009)Doi:10.1021/ol9015755
(2009)Doi:10.1055/s-0029-1217335
(2009)Doi:10.1055/s-0029-1217358
(2009)
