A convenient method for the preparation of n-heterocyclic bromophosphines: excellent precursors to the corresponding n-heterocyclic phosphenium salts

DOI: 10.1021/om900420g

Source and publish data:

Organometallics p. 4377 - 4384 (2009)

Update date:2022-07-29

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Authors:

Dube, Jonathan W.

Farrar, Gregory J.

Norton, Erin L.

Szekely, Kara L. S.

Cooper, Benjamin F. T.

Macdonald, Charles L. B.

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Article abstract of DOI:10.1021/om900420g

An in situ redox method is employed to prepare N-heterocyclic bromophosphines in good yield and purity. Such bromophosphines may be treated with a variety of bromide-abstracting reagents to produce the corresponding N-heterocyclic phosphenium salts in exc

Full text of DOI:10.1021/om900420g

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