Chemistry of Heterocyclic Compounds p. 281 - 284 (1988)
Update date:2022-07-29
Topics:
Anisimova
Askalepova
Bagdasarov
Chernov'yants
Refluxing 2-cyanomethylbenzimidazole in alcohol with alkyl halides led to low yields of N-alkylated products. Addition of base to the reaction mixture shifted the course of the reaction to form mainly N,C-dialkyl substituted products. In DMF or with an excess of alkyl halide at elevated temperature both N-mono- and N,N-dialkyl substituted materials were formed together.
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