Tetrahedron Letters p. 2047 - 2050 (1988)
Update date:2022-08-03
Topics:
Reckendorf, Wolfgang Meyer zu
Sandner, Stefan
The alkaline hydrolysis of 2-deoxy-1,3,4,6-tetra-O-acetyl-2-trimethylammonio-α-D-glucopyranose chloride leads to an unexpected product.Contrary to the hydrolysis under acidic conditions yielding 2-deoxy-2-trimethylammonio-D-glucose we obtained the corresponding 3,6-anhydro derivative by reaction with sodium hydroxide or ammonia in methanol.
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