Nine-membered metallacyclic metaloxycarbene complexes by means of sequential coupling of butadiene with a ketone and a metal carbonyl at bis(cyclopentadienyl)zirconium

DOI: 10.1021/om00104a027

Source and publish data:

Organometallics p. 450 - 454 (1989)

Update date:2022-08-04

Topics:

Authors:

Erker, Gerhard

Sosna, Friedrich

Zwettler, Roland

Krüger, Carl

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Article abstract of DOI:10.1021/om00104a027

The metallacyclic zirconoxycarbene complexes Cp₂Zr(η³-C₃H₄)CH ₂C[=M(CO)₅]O (3) (M = Cr, Mo, W) were prepared by reacting M(CO)₆ with (butadiene)ZrCp₂. The (π-allyl)Zr

Full text of DOI:10.1021/om00104a027

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Product name:Cp₂ZrOC(C₆H₅)(Me)CH₂CH=CHCH₂C{=W(CO)5}O

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