Cleavage of Cyclic Ethers Including Oxetane and Oxolane with a Highly Nucleophilic Species of Phenylselenide Anion

DOI: 10.1246/cl.1988.931

Source and publish data:

Chemistry Letters p. 931 - 934 (1988)

Update date:2022-08-02

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Authors:

Haraguchi, Kazuhiro

Tanaka, Hiromichi

Hayakawa, Hiroyuki

Miyasaka, Tadashi

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Article abstract of DOI:10.1246/cl.1988.931

Phenylselenide anion generated from (PhSe)2 and LiAlH4 was found to be highly reactive to various types of cyclic ethers, providing a new method to prepare γ- and δ-phenylselenenyl alcohols from oxetane and oxolane, respectively.

Full text of DOI:10.1246/cl.1988.931

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