Synthesis of (trimethylsilyl)(cyclopropyl)acetylenes and terminal cyclopropylacetylenes via an arsonium ylide under phase-transfer conditions

DOI: 10.1016/0022-328X(89)85204-0

Source and publish data:

Journal of Organometallic Chemistry p. 31 - 34 (1989)

Update date:2022-09-26

Topics: Synthesis Acetylenes phase-transfer conditions Trimethylsilyl Cyclopropyl

Authors:

Shen, Yanchang

Liao, Qimu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(89)85204-0

The phase-transfer reaction of 3-(trimethylsilyl)-2-propynylidenetriphenylarsorane generated from the corresponding arsonium salt and aqueous sodium hydroxide with substituted chalcones gave (trimethylsilyl)(cyclopropyl)acetylenes in 83-98percent yields w

Full text of DOI:10.1016/0022-328X(89)85204-0

Products guided by the article

Product name:[(1S,2R,3R)-2-(3-Bromo-phenyl)-3-trimethylsilanylethynyl-cyclopropyl]-phenyl-methanone

Cas No:117953-01-2

R&D Labs maybe for 117953-01-2

Weifang Jahwa Chemical Co.,Ltd

Contact:0086-536-8897731,8897730

Address:No.5166 East Dongfeng Street,Weifang,Shandong,China
Amadis Chemical Co., Ltd.

website:http://www.amadischem.com

Contact:86-571-89925085

Address:Watts Cosine.No.166.Xiangmao Road.
Beijing Apis Biotechnology Co., Ltd.

Contact:86-010-67856775-8551

Address:NO.4PUHUANGYU ROAD,FENTAI DISTRICT, BEIJING, CHINA
Taizhou volsen chemical Co., Ltd

website:http://www.volsenchem.com

Contact:+86-576-88869393

Address:Jiaojiang District, Taizhou, Zhejiang, China.
QINGDAO ON-BILLION INDUSTRAIL CO.,LTD

website:http://www.obn.com.cn

Contact:+86-15005320811 +86-532-80681989

Address:F35 Parkson Mansion No.44-60 Zhongshan Rd.

Relevant to this article

Functional primary amines and diamines from α-aminoacids. A concise route to substituted 2-aminotetralins

Doi:10.1021/ol901263t
(2009)
Uncovering the catalytic direction of chondroitin ac exolyase-from the reducing end towards the non-reducing end

Doi:10.1074/jbc.C115.708396
(2016)
Expedient pyrrolizidine synthesis by propargylsilane addition to N-acyliminium ions followed by gold-catalyzed α-allenyl amide cyclization

Doi:10.1021/jo901393y
(2009)
Nantenine as an acetylcholinesterase inhibitor: SAR, enzyme kinetics and molecular modeling investigations

Doi:10.3109/14756361003671078
(2011)
Synthesis of tert-butyl 6-oxo-2-azaspiro[3.3]heptane-2-carboxylate

Doi:10.1021/ol901325s
(2009)
New thiazolidinone and triazinethione conjugates derived from amino-β-lactams

Doi:10.3987/COM-09-11668
(2009)

Article Doi