A novel one-pot synthesis of 2,4-enynyl amides

DOI: 10.1080/00397919108019804

Source and publish data:

Synthetic Communications p. 1991 - 1998 (1991)

Update date:2022-08-05

Topics:

Authors:

Shen Shen

Xiang Xiang

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Article abstract of DOI:10.1080/00397919108019804

Silylated 2,4-enynyl amides can be synthesized by the reaction of 3-(trimethylsilyl)-2-propynylidenetriphenylarsorane, generated in situ from the corresponding arsonium salt and n-butyllithium, with α-bromoacetamides in 40-59% yields (two steps) and with

Full text of DOI:10.1080/00397919108019804

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Product name:Triphenyl-(3-trimethylsilanyl-prop-2-ynylidene)-λ⁵-arsane

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