A New and General Synthesis of α-Silyl Carbonyl Compounds by Si-H Insertion from Transition Metal Catalyzed Reactions of Diazo Esters and Diazo Ketones

DOI: 10.1021/jo00261a045

Source and publish data:

Journal of Organic Chemistry p. 6158 - 6160 (1988)

Update date:2022-08-04

Topics:

Authors:

Bagheri, Vahid

Doyle, Michael P.

Taunton, Jack

Claxton, E. Elizabeth

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Article abstract of DOI:10.1021/jo00261a045

α-Silyl esters and α-silyl ketones are formed in high yield by Rh2(OAc)4- or Cu(acac)2-catalyzed decomposition of diazo esters and diazo ketones in the presence of organosilanes.

Full text of DOI:10.1021/jo00261a045

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