On the Use of Epoxy Alcohol-Aldol Rearrangement for Stereoselective Construction of Quarternary Carbon Centers

DOI: 10.1016/S0040-4039(01)81083-2

Source and publish data:

Tetrahedron Letters p. 5891 - 5894 (1987)

Update date:2022-08-04

Topics:

Authors:

Shimazaki, Masato

Hara, Hisaaki

Suzuki, Keisuke

Tsuchihashi, Gen-ichi

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Article abstract of DOI:10.1016/S0040-4039(01)81083-2

A new method for the construction of quarternary carbon centers is reported, which is based on the Lewis acid-promoted 1,2-rearrangement of β,γ-epoxy alcohols giving α,α-disubstituted aldols stereospecifically in high yields.

Full text of DOI:10.1016/S0040-4039(01)81083-2

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