Tetrahedron Letters p. 5891 - 5894 (1987)
Update date:2022-08-04
Topics:
Shimazaki, Masato
Hara, Hisaaki
Suzuki, Keisuke
Tsuchihashi, Gen-ichi
A new method for the construction of quarternary carbon centers is reported, which is based on the Lewis acid-promoted 1,2-rearrangement of β,γ-epoxy alcohols giving α,α-disubstituted aldols stereospecifically in high yields.
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Doi:10.1021/ol500022n
(2014)Doi:10.1246/cl.1994.941
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(2014)Doi:10.1021/acs.joc.6b02388
(2017)Doi:10.1021/acs.orglett.0c01650
(2020)
