Tetrahedron Letters p. 5891 - 5894 (1987)
Update date:2022-08-04
Topics:
Shimazaki, Masato
Hara, Hisaaki
Suzuki, Keisuke
Tsuchihashi, Gen-ichi
A new method for the construction of quarternary carbon centers is reported, which is based on the Lewis acid-promoted 1,2-rearrangement of β,γ-epoxy alcohols giving α,α-disubstituted aldols stereospecifically in high yields.
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Doi:10.1021/ol500022n
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