Synthesis of (1S,2R)- and (1S,2S)-1-Aminocyclopropane-1-carboxylic Acids: The Total 1H NMR Assignment of Cyclo

Article abstract of DOI:10.1021/jo00263a004

An asymmetric synthesis of stereospecifically monodeuteriated ACC's, (1S,2R)- and (1S,2S)-1-amino<2-2H>cyclopropane-1-carboxylic acids, is described.The reduction of methyl (Z)-2-acetamido-4-methoxybut-2-enoate with 2H2 gas in the presence of the asymmetr