Journal of the Chemical Society. Perkin transactions I p. 1173 - 1178 (1988)
Update date:2022-08-05
Topics:
Crabb, Trevor A.
Trethewey, Andrew N.
Takeuchi, Yoshito
The position of conformational equilibria (CDCl3 solution; 298 K) of perhydrothiazolo<3,4-a>pyridine and the corresponding 6-ethyl-substituted derivatives have been determined by (1)H and (13)C n.m.r. spectroscopy.The reported synthesis of the 1-methylperhydrothiazolo<3,4-a>pyridines via 1-bromo-1-(2-piperidyl)ethane hydrobromide gave in addition the isomeric 9-methylperhydro-3,8-methano-1,3-thiazocines.Contrary to an earlier report trans-(1H,8aH)-1-methylperhydrothiazolo<3,4-a>pyridine was found to adopt an 87percent trans-fused <*> 13percent cis-fused conformational equilibrium (CDCl3; 193 K).
View Morewebsite:http://www.easchem.com
Contact:+86-731-89722861 89722891
Address:2/F-4/Bld Colorful Palace, No.605 Changsha Ave, Yuhua Area Changsha Hunan China.
Jinan Boss Chemical Industry Co., Ltd.【revoke the business license】
website:http://www.chemboss.com.cn
Contact:+86-531-58591595
Address:No2.Hualong Road, Jinan, China
FUJIAN SHANSHUI CHEMICAL CORP.LTD.
Contact:+86-151-59920036
Address:Jinqiao Gareden, jo@fj-xinyi.com
Rugao Jinling Chemical Co., Ltd.(expird)
Contact:0086-513-68005586
Address:Lianluo new village huangshi town Rugao city Jiangsu Province.
Jiangxi Lanqi Fine Chemical S&T Co., Ltd.
Contact:+86-21-64891143
Address:XinJiShan Industrial Area, Zhangshu City, JiangXi Province, China
Doi:10.1016/0040-4039(88)85044-5
(1988)Doi:10.1021/ol901236s
(2009)Doi:10.1007/s11172-009-0180-6
(2009)Doi:10.1016/j.tet.2008.09.003
(2008)Doi:10.1016/j.tetlet.2008.09.122
(2008)Doi:10.1021/jo802345f
(2009)
