New Molecular Hydrogen Iron(II) Complexes: Synthesis, Characterization, and Reactivity with Aryldiazonium Cations

DOI: 10.1021/ja00188a021

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Journal of the American Chemical Society p. 2072 - 2077 (1989)

Update date:2022-08-04

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Authors:

Albertin, Gabriele

Antoniutti, Stefano

Bordignon, Emilio

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Article abstract of DOI:10.1021/ja00188a021

Dihydrogen complexes of the type 2-H2)P4>BPH4 were prepared by allowing the dihydride FeH2P4 to react at -80 deg C with HBF4*Et2O in ethanol.Variable-temperature ¹H and ³¹P<¹H> NMR

Full text of DOI:10.1021/ja00188a021

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Product name:{cis-FeH(P(OEt)3)(PPh(OEt)2)4}(BPh₄)

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