Tetrahedron Letters p. 4899 - 4902 (2009)
Update date:2022-08-04
Topics: Synthesis Catalyst Nucleophile Steric hindrance Stereoselective synthesis Pyrrolidine Stereoselectivity Organic compound Strategy
Gresser, Mary J.
Keller, Paul A.
Wales, Steven M.
A new strategy for the stereoselective synthesis of the 2,2′-bipyrrolidine scaffold is presented using a metathesis reaction followed by asymmetric dihydroxylation for the introduction of the stereogenic elements. This straightforward high-yielding process is suitable for application to the synthesis of additional heterocycles.
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