Journal of the Chemical Society. Chemical communications p. 1532 - 1534 (1987)
Update date:2022-09-26
Topics:
Okada, Yoshio
Iguchi, Shin
Kawasaki, Koichi
β-1 and β-2-Adamantylaspartates, H-Asp(O-1-Ada)-OH and H-Asp(O-2-Ada)-OH respectively, were synthesized and their properties examined, showing possible application in solid-phase peptide synthesis when used in combination with the fluoren-9-ylmethoxycarbonyl (Fmoc) group, as an Nα-protecting group; both these new protecting groups can suppress aspartimide formation as a side reaction under acidic and basic conditions.
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