Journal of the Chemical Society. Chemical communications p. 828 - 829 (1988)
Update date:2022-08-05
Topics:
Baldwin, Jack E.
North, Michael
Flinn, Anthony
Moloney, Mark G.
Reaction of α-t-butyl γ-methyl N-trityl-L-glutamate (7) with lithium isopropylcyclohexylamide in hexane leads to the specific formation of the γ-ester enolate, a potential synthetic equivalent to the γ-anion synthon for stereospecific α-amino acid synthesis.
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