ALKALI METAL-LIQUID AMMONIA REDUCTION OF γ-LACTONES TO DIOLS AND CYCLIC HEMIACETALS: STEREOCHEMICAL INFLUENCE BY THE NEIGHBOURING GROUP ON THE NATURE OF THE PRODUCTS

DOI: 10.1016/S0040-4020(01)90319-9

Source and publish data:

Tetrahedron p. 4433 - 4438 (1987)

Update date:2022-08-03

Topics:

Authors:

Chakraborti, Asit K.

Saha, Bijali

Ray, Chhanda

Ghatak, Usha Ranjan

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Article abstract of DOI:10.1016/S0040-4020(01)90319-9

Lithium or sodium-liquid ammonia reduction of 3-hydroxy-1,3-dimethylcyclohexane-1,3-carbolactones (5), (6) and (7) with or without a C-2 equatorial substituent gives the respective diols (8), (9) and (10), whereas the lactones (11) and (12), having a C-2

Full text of DOI:10.1016/S0040-4020(01)90319-9

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