
Chemistry Letters p. 1557 - 1560 (1987)
Update date:2022-08-04
Topics:
Tian, Guan Rong
Sugiyama, Shigeru
Mori, Akira
Takeshita, Hitoshi
The Diels-Alder adduct of tropone with 2,3-bis(methoxycarbonyl)-7-oxabicyclo<2.2.1>hepta-2,5-diene formed homobarrelenone by heating at ca. 130 deg C.Similarly prepared were 1-hydroxy-, 3-methoxy-, 1-chloro-, and 3-chlorohomobarrelenones.High-pressure cycloaddition improved the yields of the Diels-Alder adducts.
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