Monatshefte fur Chemie p. 243 - 248 (1983)
Update date:2022-08-03
Topics:
Koepf, Hartmut
Klouras, Nikolaos
PhPCp2 could be prepared by the reaction of PhPCl2 with CpNa.The metallation of PhPCp2 with n-BuLi and the following reaction with TiCl4 led to the first P-bridged <1>titanocenophane.Structural assignments of this compound could be made on the base of its 1H-NMR spectrum. - Keywords: Phenylbis(cyclopentadienyl)phosphane; P-Phenyl-1,1'-phosphanediylbis(cyclopentadienyl)titanium(IV) dichloride; <1>Titanocenophanes
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