The First Phosphorus-Bridged Titanocenophanes

Article abstract of DOI:10.1007/BF00798327

PhPCp2 could be prepared by the reaction of PhPCl2 with CpNa.The metallation of PhPCp2 with n-BuLi and the following reaction with TiCl4 led to the first P-bridged <1>titanocenophane.Structural assignments of this compound could be made on the base of its 1H-NMR spectrum. - Keywords: Phenylbis(cyclopentadienyl)phosphane; P-Phenyl-1,1'-phosphanediylbis(cyclopentadienyl)titanium(IV) dichloride; <1>Titanocenophanes