Synthesis and Absolute Configuration of the Aristotelia Alkaloid Peduncularine

DOI: 10.1021/ja00189a036

Source and publish data:

Journal of the American Chemical Society p. 2588 - 2595 (1989)

Update date:2022-09-26

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Authors:

Klaver, Wim J.

Hiemstra, Henk

Speckamp, W. Nico

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Article abstract of DOI:10.1021/ja00189a036

The first synthesis of the Aristotelia alkaloid peduncularine (1) is described.The synthetic sequence commences with (S)-malic acid and amounts to 16 steps.Key transformations are (1) the stereoselective transalkylation of the β-hydroxylactam dianion deri

Full text of DOI:10.1021/ja00189a036

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