Journal of the American Chemical Society p. 2588 - 2595 (1989)
Update date:2022-09-26
Topics:
Klaver, Wim J.
Hiemstra, Henk
Speckamp, W. Nico
The first synthesis of the Aristotelia alkaloid peduncularine (1) is described.The synthetic sequence commences with (S)-malic acid and amounts to 16 steps.Key transformations are (1) the stereoselective transalkylation of the β-hydroxylactam dianion deri
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