THE REACTION OF α,β-EPOXYSILANES WITH METALLATED ALKYLARYL SULPHONES. A NOVEL APPROACH TO ALLYLIC ALCOHOLS

DOI: 10.1016/S0040-4039(00)87917-4

Source and publish data:

Tetrahedron Letters p. 2497 - 2500 (1988)

Update date:2022-08-03

Topics:

Authors:

Masnyk, Marek

Wicha, Jerzy

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Article abstract of DOI:10.1016/S0040-4039(00)87917-4

Lithiated alkylaryl sulphones (2a-c) react with α,β-epoxysilane (1) to yield O-trimethylsilyl allylic alcohols (3a-c), predominantly as Z isomers.The BF3-assisted reaction followed by treatment of the adduct with nBu4NF affords allylic alcohols.

Full text of DOI:10.1016/S0040-4039(00)87917-4

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