Tetrahedron Letters p. 2497 - 2500 (1988)
Update date:2022-08-03
Topics:
Masnyk, Marek
Wicha, Jerzy
Lithiated alkylaryl sulphones (2a-c) react with α,β-epoxysilane (1) to yield O-trimethylsilyl allylic alcohols (3a-c), predominantly as Z isomers.The BF3-assisted reaction followed by treatment of the adduct with nBu4NF affords allylic alcohols.
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