Green Chemistry p. 2976 - 2981 (2014)
Update date:2022-09-26
Topics:
Li, Yu
Xiong, Yan
Li, Xueming
Ling, Xuege
Huang, Ruofeng
Zhang, Xiaohui
Yang, Jianchun
An efficient and environmentally friendly benzylation of arenes with benzyl ethers as benzyl donors using BF3-Et2O to generate in situ the superacid BF3-H2O as an efficient promotor has been described. A wide variety of functional groups have been investigated and found to be compatible to give the desired diarylmethanes in yields of up to 99%. The crucial role of the moisture content in this transformation has been demonstrated by detailed investigations. This journal is the Partner Organisations 2014.
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