Palladium(0)-Based Approach to Functionalized C-Glycopyranosides

DOI: 10.1021/jo00269a026

Source and publish data:

Journal of Organic Chemistry p. 1890 - 1896 (1989)

Update date:2022-08-02

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Authors:

Brakta, Mohamed

Lhoste, Paul

Sinou, Denis

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Article abstract of DOI:10.1021/jo00269a026

Phenyl 4,6-di-O-benzyl-2,3-dideoxy-D-erythro-hex-2-enopyranoside 4α or 5β reacts with ethyl malonate, acetylacetone, methyl acetylacetate, ethyl nitroacetate, and ethyl nitromalonate under neutral conditions in the presence of Pd(0) to give regiospecifica

Full text of DOI:10.1021/jo00269a026

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Product name:ethyl 2-(4',6'-di-O-benzyl-2',3'-dideoxy-β-D-erythro-hex-2'-enopyranosyl)-2-nitro-2-(ethoxycarbonyl)acetate

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