Bulletin of the Chemical Society of Japan p. 475 - 482 (1988)
Update date:2022-08-04
Topics:
Takekuma, Shin-ichi
Marsubara, Yoshiharu
Yamamoto, Hiroshi
Nozoe, Tetsuo
Autooxidation of Guaiazulene was examined in detail under the following conditions: in a highly diluted DMF solution, in DMF in the presence of acid or base (at 80-100 deg C), and as solid state under sunlight or in the dark (at 25-50 deg C).In all cases a wide variety of products were obtained (33 separable compounds altogether), and a comparable study on the distribution of the products under the various reaction conditions was made to establish more precise reaction pathways for the formation of these interesting compounds.
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