Radical Cyclization of N-(Cyclohex-2-enyl)-α,α-dichloroacetamides. Stereoselective Syntheses of (+/-)-Mesembranol and (+/-)-Elwesine

DOI: 10.1021/jo00001a021

Source and publish data:

Journal of Organic Chemistry p. 95 - 102 (1991)

Update date:2022-08-03

Topics:

Authors:

Ishibashi, Hiroyuki

So, Taru Su

Okochi, Kyoko

Sato, Tatsunori

Nakamura, Nobuyuki

et al. et al.

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Article abstract of DOI:10.1021/jo00001a021

Stereoselective syntheses of the Sceletium alkaloid (+/-)-mesembranol (2) and the Amaryllidaceae alkaloid (+/-)-elwesine (3) have been achieved.A key step in the syntheses involves the Bu3SnH-mediated radical cyclization of the dichloroacetamides 34 and 4

Full text of DOI:10.1021/jo00001a021

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