A Radical Cyclisation Route to 3-Alkyl Furans. Synthesis of Perillene and Dendrolasin

DOI: 10.1246/cl.1988.371

Source and publish data:

Chemistry Letters p. 371 - 372 (1988)

Update date:2022-08-03

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Authors:

Srikrishna, Adusumilli

Sunderbabu, Gajendran

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Article abstract of DOI:10.1246/cl.1988.371

A general three step synthesis of 3-alkyl furans, including Perillene and Dendrolasin, from alk-2-ynyl alcohols is described via radical cyclisation of 2-bromo-1-ethoxyethyl alk-2-ynyl ethers to 2-ethoxy-4-alkylidene tetrahydrofurans.

Full text of DOI:10.1246/cl.1988.371

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