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Biosyntheses of Antibiotic A26771B by Penicillium turbatum and Dehydrocurvularin by Alternaria cinerariae: Comparison of Stereochemistry of Polyketide and Fatty Acid Enoyl Thiol Ester Reductases

DOI: 10.1021/ja00191a042

Source and publish data:

Journal of the American Chemical Society p. 3391 - 3399 (1989)

Update date:2022-08-04

Topics: Stereochemistry   Polyketide  

Authors:

Arai, KunizoArai, Kunizo

Rawlings, Bernard J.Rawlings, Bernard J.

Yoshizawa, YukoYoshizawa, Yuko

Vederas, John C.Vederas, John C.

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Article abstract of DOI:10.1021/ja00191a042

The biosyntheses of reduced polyketides and fatty acids were compared by use of stable isotope labeling and NMR spectroscopy.Incorporations of sodium <1-(13)C>-, <2-(13)C>-, <1,2-(13)C2>-, <1-(13)C,(18)O2>-, <1-(13)C,(2)H3>-, and <2-(13)C,(2)H3>acetates i

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Full text of DOI:10.1021/ja00191a042

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