Functionalized organozincates and organocuprates derived from γ-hydroxytellurides in the preparation of 1,4-hydroxyketones

DOI: 10.1016/j.tetlet.2009.08.097

Source and publish data:

Tetrahedron Letters p. 6368 - 6371 (2009)

Update date:2022-08-04

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Authors:

Princival, Jefferson L.

Dos Santos, Alcindo A.

Comasseto, Jo?o V.

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Article abstract of DOI:10.1016/j.tetlet.2009.08.097

A C-O-dianionic zincate was generated by a Te/Li exchange reaction of an alkyltelluride, followed by Li/Zn transmetallation and reaction with methyllithium. The reaction between the enantiomerically pure (99% ee) (R)-dianionic zincate and benzoyl chloride

Full text of DOI:10.1016/j.tetlet.2009.08.097

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