Tetrahedron Letters p. 2903 - 2906 (1988)
Update date:2022-08-04
Topics:
Ohannesian, Lena
Keefer, Larry K.
Cations formed on O-coordination of N-nitrosodimethylamine with different electrophiles decomposed by different routes: dissociation of Me2N=NOCMe3(1+) ClO4(1-); regeneration of free nitrosamine by nucleophilic cleavage of the O-Si bond in Me2N=NOSiMe3(1+) CF3SO3(1-); and nucleophilic displacement of the N-methyl groups from Me2N=NOSO2CF3(1+) CF3SO3(1-).
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