Enantiospecific Syntheses of (+)- and (-)-Altholactone (Goniothalenol)

DOI: 10.1039/c39880000976

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 976 - 978 (1988)

Update date:2022-09-26

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Authors:

Gillhouley, John G.

Shing, Tony K. M.

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Article abstract of DOI:10.1039/c39880000976

(+)-Altholactone (1) and its enantiomer (2) have been synthesised from D-gulolactone and D-mannose, respectively, with stereocontrolled reduction (Et3SiH/BF3.Et2O) of the lactols (4) and (10) as a key step.

Full text of DOI:10.1039/c39880000976

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