Nickel-Catalyzed Geminal Dimethylation of Allylic Dithioacetals

DOI: 10.1021/jo00271a001

Source and publish data:

Journal of Organic Chemistry p. 2261 - 2262 (1989)

Update date:2022-08-04

Topics:

Authors:

Yang, Ping-Fan

Ni, Zhi-Jie

Luh, Tien-Yau

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00271a001

A geminal dimethyl group is introduced regioselectively in excellent yield from the reactions of allylic dithioacetals and methylmagnesium iodide in the presence of 3 mol percent of NiCl2(dppe) in refluxing ether-benzene.

Full text of DOI:10.1021/jo00271a001

Products guided by the article

Product name:(E)-1-methoxy-2-(3-methylbut-1-en-1-yl)benzene

Cas No:119925-07-4

R&D Labs maybe for 119925-07-4

Shenyang Xingzhenghe Chemical Co., Ltd.

Contact:024-23509232

Address:No. 33, Naner Road, Heping Dist.
Anhui Gusheng Import&Export CO.,LTD

Contact:86-551-63662296

Address:Jinzhai Road NO.162 ,hefei, china
Guangxi Nanning Guangtai Agriculture Chemical Co.,Ltd

Contact:+86-771-2311266

Address:Room703,Building12, Software Park Phase II,NO.68,Keyuan Road,Nanning City,Guangxi,China
Shenyang Xinyihan Chemical Technology Co., Ltd.

Contact:+86-18525026267

Address:362, aigongbeijei street 23 , tiexi district,Shenyang, Liaoning, China
Xi'an Yuri Solar Co., Ltd

website:https://www.yurisolar.com/en

Contact:86--18092602675

Address:No. 560, East Hangtian Road, Xi'an, China

Relevant to this article

9-Arylpurines as a novel class of enterovirus inhibitors

Doi:10.1021/jm901240p
(2010)
Various synthetic routes to a gable-like bis(porphyrin) constructed on a 1,10-phenanthroline chelate

Doi:10.1002/ejoc.200900149
(2009)
Synthetic Methods for the Preparation of D- and L-Pseudo-Sugars from D-Glucose

Doi:10.1039/c39880001184
(1988)
The First Tandem [2 + 2] Cycloaddition-Michael Reaction Using Ynolates: Facile Construction of Substituted Carbocycles

Doi:10.1021/ol0159928
(2001)
Discovery of a Novel and Brain-Penetrant O-GlcNAcase Inhibitor via Virtual Screening, Structure-Based Analysis, and Rational Lead Optimization

Doi:10.1021/acs.jmedchem.0c01712
(2021)
Preparation, facile deprotonation, and rapid H/D exchange of the μ-hydride diiron model complexes of the [FeFe]-hydrogenase containing a pendant amine in a chelating diphosphine ligand

Doi:10.1021/ic901154m
(2009)

Article Doi