Nickel-Catalyzed Geminal Dimethylation of Allylic Dithioacetals

DOI: 10.1021/jo00271a001

Source and publish data:

Journal of Organic Chemistry p. 2261 - 2262 (1989)

Update date:2022-08-04

Topics:

Authors:

Yang, Ping-Fan

Ni, Zhi-Jie

Luh, Tien-Yau

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Article abstract of DOI:10.1021/jo00271a001

A geminal dimethyl group is introduced regioselectively in excellent yield from the reactions of allylic dithioacetals and methylmagnesium iodide in the presence of 3 mol percent of NiCl2(dppe) in refluxing ether-benzene.

Full text of DOI:10.1021/jo00271a001

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