
Journal of Organic Chemistry p. 2047 - 2050 (1989)
Update date:2022-08-05
Topics: Regioselectivity GC-MS Column chromatography Yield NMR spectroscopy Selectivity Ligand Heck reaction Palladium-Catalyzed TLC (thin-layer chromatography) Oxidative Addition Reductive Elimination Solvent Effects Stereoselectivity Vinylation Substrate Catalytic Cycle Intermolecular β-Hydride Elimination Cyclic alkenes Inert atmosphere Schlenk line Turnover frequency (TOF) Turnover number (TON) π-Complexation
Larock, Richard C.
Gong, William H.
Vinylic halides or triflates and cyclic alkenes undergo facile, palladium-catalyzed, intermolecular, allylic cross-coupling under mild reaction conditions to afford excellent yields of 1,4-dienes.
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