Enantiodifferentiating Functionalization of cis-Cycloalkane-1,2-diols and cis-endo-5-Norbornen-2,3-ylenebis(methanol) via Chiral Spiroacetals Derived from 1-Menthone

DOI: 10.1021/jo00272a027

Source and publish data:

Journal of Organic Chemistry p. 2599 - 2605 (1989)

Update date:2022-07-30

Topics:

Authors:

Harada, Toshiro

Wada, Isao

Oku, Akira

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00272a027

The enantiodifferentiating transformation of a prochiral hydroxyl group in cis-cycloalkane-1,2-diols and cis-endo-5-norbornen-2,3-ylenebis(methanol) (16) is presented.The reactions of the bis(trimethylsilyl) derivatives of 1,2-diols 6a-d with l-menthone i

Full text of DOI:10.1021/jo00272a027

Products guided by the article

Product name:2-[(1R,2S,5R)-1-((1R,2S,3R,4S)-3-Hydroxymethyl-bicyclo[2.2.1]hept-5-en-2-ylmethoxy)-2-isopropyl-5-methyl-cyclohexyl]-1-phenyl-ethanone

Cas No:119972-94-0

R&D Labs maybe for 119972-94-0

Shanghai Pengkai Chemical Co.,Ltd

Contact:+86-21-60526671

Address:No.4226 Duzhuang Rd Minhang District Shanghai China
Zhejiang Tianyu Pharmaceutical Co., Ltd.

Contact:+86-576-84177669, 89189665,89189688,84168770

Address:Jiangkou Development Zone, Huangyan, Taizhou City, Zhejiang
Jiangxi Biochem Co.,Ltd

Contact:86-791-86629460

Address:1-6F, 118 Xinzhou road, Nanchang, Jiangxi, China
Hangzhou Yingshanhua Pigment Chemicals Co.,Ltd.

Contact:+86-0150-58101658

Address:Nanyang Economic DevelopmentZong,Xiaoshan,Hangzhou,China
Chengdu D-Innovation Pharmaceutical Co., Ltd

Contact:86-28-85105536

Address:1001, B6, No.88 Keyuan South Road, Chengdu Hi-Tech Zone

Relevant to this article

2,6-Disubstituted benzoates as neighboring groups for enhanced diastereoselectivity in β-galactosylation reactions: Synthesis of β-1,3-linked oligogalactosides related to arabinogalactan proteins

Doi:10.1021/jo902100q
(2009)
IDENTIFICATION OF DERIVATIVES OF 2H-CHROMENES AND THEIR ACYCLIC TAUTOMERIC FORMS IN THE GAS PHASE BY MASS SPECTROMETRY

Doi:10.1007/BF00475592
(1988)
Structural evolution study of substituted wustites Fe_1-z-y(Ca, Mg)_yO

Doi:10.1016/0022-3697(90)90075-Q
(1990)
Ring expansion of oxyglycals. Synthesis and conformational analysis of septanoside-containing trisaccharides

Doi:10.1021/jo901945e
(2010)
Spiro-Fused 2,5-Cyclohexadienones from the Thermal 1,3-Alkyl Migrations of Quinol Vinyl Ethers. A Strategy for Conversion of a Carbonyl Carbon to a Quaternary Carbon

Doi:10.1021/jo00283a035
(1989)
Assembly of heteroleptic copper complexes with silver salts: from discrete trinuclear complexes to infinite networks

Doi:10.1021/ic902057d
(2010)

Article Doi