Enantiodifferentiating Functionalization of cis-Cycloalkane-1,2-diols and cis-endo-5-Norbornen-2,3-ylenebis(methanol) via Chiral Spiroacetals Derived from 1-Menthone

DOI: 10.1021/jo00272a027

Source and publish data:

Journal of Organic Chemistry p. 2599 - 2605 (1989)

Update date:2022-07-30

Topics:

Authors:

Harada, Toshiro

Wada, Isao

Oku, Akira

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00272a027

The enantiodifferentiating transformation of a prochiral hydroxyl group in cis-cycloalkane-1,2-diols and cis-endo-5-norbornen-2,3-ylenebis(methanol) (16) is presented.The reactions of the bis(trimethylsilyl) derivatives of 1,2-diols 6a-d with l-menthone i

Full text of DOI:10.1021/jo00272a027

Products guided by the article

Product name:2-[(1R,2S,5R)-1-((1R,2S,3R,4S)-3-Hydroxymethyl-bicyclo[2.2.1]hept-5-en-2-ylmethoxy)-2-isopropyl-5-methyl-cyclohexyl]-1-phenyl-ethanone

Cas No:119972-94-0

R&D Labs maybe for 119972-94-0

Sigma-Aldrich Chemie GmbH

website:http://www.sigmaaldrich.com

Contact:800 558-9160

Address:Industriestrasse 25CH-9471 Buchs SGSwitzerland
Longhui qunfeng Chemical Co., Ltd

Contact:86-731-82173407

Address:South-east Industrial Park, Longhui County, Hunan Province, China
Xinchang Jiu Xin Pharmaceutical Co., Ltd

website:http://www.jiuxinpharm.com

Contact:86 137 5756 8585

Address:Poyang industry Park
Chengdu King-tiger Pharm-chem. Tech. Co., Ltd

Contact:028-85317716

Address:Tianfu Life Science Park, No. 88 South Keyuan Road, Gaoxin District, Chengdu City, Sichuan Province, PRC.
Xinchang Jiu Xin Pharmaceutical Co., Ltd

website:http://www.jiuxinpharm.com

Contact:86 137 5756 8585

Address:Poyang industry Park

Relevant to this article

2,6-Disubstituted benzoates as neighboring groups for enhanced diastereoselectivity in β-galactosylation reactions: Synthesis of β-1,3-linked oligogalactosides related to arabinogalactan proteins

Doi:10.1021/jo902100q
(2009)
IDENTIFICATION OF DERIVATIVES OF 2H-CHROMENES AND THEIR ACYCLIC TAUTOMERIC FORMS IN THE GAS PHASE BY MASS SPECTROMETRY

Doi:10.1007/BF00475592
(1988)
Structural evolution study of substituted wustites Fe_1-z-y(Ca, Mg)_yO

Doi:10.1016/0022-3697(90)90075-Q
(1990)
Ring expansion of oxyglycals. Synthesis and conformational analysis of septanoside-containing trisaccharides

Doi:10.1021/jo901945e
(2010)
Spiro-Fused 2,5-Cyclohexadienones from the Thermal 1,3-Alkyl Migrations of Quinol Vinyl Ethers. A Strategy for Conversion of a Carbonyl Carbon to a Quaternary Carbon

Doi:10.1021/jo00283a035
(1989)
Assembly of heteroleptic copper complexes with silver salts: from discrete trinuclear complexes to infinite networks

Doi:10.1021/ic902057d
(2010)

Article Doi