Enantiodifferentiating Functionalization of cis-Cycloalkane-1,2-diols and cis-endo-5-Norbornen-2,3-ylenebis(methanol) via Chiral Spiroacetals Derived from 1-Menthone

DOI: 10.1021/jo00272a027

Source and publish data:

Journal of Organic Chemistry p. 2599 - 2605 (1989)

Update date:2022-07-30

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Authors:

Harada, Toshiro

Wada, Isao

Oku, Akira

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Article abstract of DOI:10.1021/jo00272a027

The enantiodifferentiating transformation of a prochiral hydroxyl group in cis-cycloalkane-1,2-diols and cis-endo-5-norbornen-2,3-ylenebis(methanol) (16) is presented.The reactions of the bis(trimethylsilyl) derivatives of 1,2-diols 6a-d with l-menthone i

Full text of DOI:10.1021/jo00272a027

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