IRON-MEDIATED AROMATIC ALLYLATION

DOI: 10.1016/S0040-4039(00)96742-X

Source and publish data:

Tetrahedron Letters p. 5415 - 5418 (1987)

Update date:2022-08-04

Topics:

Authors:

Dieter, Janice W.

Li, Zhong

Nicholas, Kenneth M.

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Article abstract of DOI:10.1016/S0040-4039(00)96742-X

Electron rich aromatic and heteroaromatic compounds react with (η³-allyl)Fe(CO)4BF4 to produce allylated aromatics in moderate to good yields.Unsymmetrically substituted allyl complexes afford the corresponding butenyl-, 1,1-dimethylallyl-, cinnamyl-, and geranyl-derivatives with moderate to excellent regioselectivity and complete stereoselectivity.

Full text of DOI:10.1016/S0040-4039(00)96742-X

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