Diastereofacial Control in the Reaction of (R)-α-(p-Tolylsulfinyl)acetophenones with Several Organometallics

DOI: 10.1246/cl.1988.1541

Source and publish data:

Chemistry Letters p. 1541 - 1544 (1988)

Update date:2022-09-26

Topics:

Authors:

Fujisawa, Tamotsu

Fujimura, Atsushi

Ukaji, Yutaka

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1988.1541

The diastereofacial controlled addition of organometallics to optically active β-ketosulfoxide was achieved to furnish both diastereomers of β-hydroxy sulfoxide depending on the selection of organometallic reagents.Trichloromethyltitanium added to (R)-α-(

Full text of DOI:10.1246/cl.1988.1541

Products guided by the article

Product name:(S)-2-[2-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-phenyl]-1-((R)-toluene-4-sulfinyl)-propan-2-ol

Cas No:120342-16-7

R&D Labs maybe for 120342-16-7

Weifang Arylchem Chemical Co., LTD

Contact:86-536-5217866

Address:Development Zone, Shouguang, Shandong Province
RongCheng K&S Chemical Co.,Ltd

Contact:0631-7336369

Address:rongcheng ,shandong province china
Hangzhou jls Flame Retardants Chemical Co.,Ltd

Contact:+86-571-87250387/87250386

Address:MOGANSHAN RODA 1418# SHANGCHENG INDUSTRIAL PARK
Beijing Wisdom Chemicals Co., Ltd.

Contact:+86-10-52350335

Address:F2, BLDG 19, Liando Valley U, Majuqiao, Tongzhou District, Beijing, China
Jining Shengrun Chemical Industry Co., Ltd.

Contact:+86-537-7121666 ,

Address:West Ring Road,Wenshang County Shandong Province

Relevant to this article

Ring expansion of 2-alkenyl azetidines into unsaturated azocanes

Doi:10.1055/s-0029-1218351
(2009)
Metal free, click and click-click conjugation of ribonucleosides and 2′-OMe oligoribonucleotides on the solid phase

Doi:10.1039/b918463e
(2010)
A novel approach to carbocyclic analogues of nucleosides

Doi:10.1016/S0040-4039(00)94255-2
(1986)
A recyclable metal-organic framework MOF-199 catalyst in coupling and cyclization of β-bromo-α,β-unsaturated carboxylic acids with terminal alkynes leading to alkylidenefuranones

Doi:10.1016/j.jorganchem.2015.05.040
(2015)
Expedient access to branched allylic silanes by copper-catalysed allylic substitution of linear allylic halides

Doi:10.1039/b920793g
(2010)
Identification of 2-anilino-9-methoxy-5, 7-dihydro-6H-pyrimido[5, 4-d][l]benzazepin-6-ones as dual PLK1/VEGF-R2 kinase inhibitor chemotypes by structure-based lead generation

Doi:10.1021/jm901388c
(2010)

Article Doi