Journal of Physical Chemistry p. 4802 - 4806 (1989)
Update date:2022-08-03
Topics:
Bonneau, Roland
Liu, Michael T. H.
Suresh, R. V.
Laser flash photolysis studies of the reaction of benzylbromocarbene with pyridine enables the determination of the absolute rate constant for the 1,2-hydrogen migration in benzybromocarbene.Thus, k= 5.6E7/s-1 at 25 deg C.Relative reactivities of benzylbromocarbene toward electron-poor and electron-rich alkenes indicate that the carbene is ambiphilic.The present results are consistent with a mechanism involving a carbene-alkene intermediate.
View MoreTaizhou Chenyi chemical co. LTD,
Contact:13736652831
Address:NO.273 SHANGHAI SOUTH STREET,LUQIAO DISTRICT,ZHEJIANG PROVINCE,CHINA.
Nantong Auxin Electronic Technology Co., LTD
Contact:86-513-88760026
Address:NO.5-1, Aoxin Road, Haian Hi-tech Development Zone, Jiangsu Province, China
Shanghai agrotree chemical co.,ltd.
Contact:+86-21-50117563
Address:Room 8A,liangfeng building,No.8 dongfang RD.pudong,shanghai,China
Sanming Coffer Fine Chemical Industrial Co., Ltd
website:http://www.cofferxm.com/
Contact:+86-598-5853979
Address:Jin-sha Yuan Chuang-ye Park,Hi-Tech Development Zone,Sanming City P.R.China
Shanghai shibo Chemical Co., Ltd
Contact:+86-021-60753516
Address:688 Qiushi Road, Jinshan High-tech Park, Shanghai, China,201512
Doi:10.1002/jhet.211
(2009)Doi:10.1055/s-0030-1258965
(2010)Doi:10.1039/b917045f
(2010)Doi:10.1021/np900622m
(2010)Doi:10.1016/j.tet.2009.11.036
(2010)Doi:10.1039/c3lc51195b
(2014)