Palladium-Catalyzed Carbonylation of Allylamines. Synthesis of β,γ-Unsaturated Amides by One-Carbon Homologation of Allylamines

DOI: 10.1016/S0040-4020(01)80767-5

Source and publish data:

Tetrahedron p. 453 - 464 (1994)

Update date:2022-08-05

Topics:

Authors:

Murahashi, Shun-Ichi

Imada, Yasushi

Nishimura, Koichi

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Article abstract of DOI:10.1016/S0040-4020(01)80767-5

Palladium-catalyzed carbonylation of allylamines under CO (50 atm) at 110 deg C proceeds highly efficiently to give the correponding β,γ-unsaturated amides.The carbonylation occurs at the less substituted carbon of allyl units to give linear amides with h

Full text of DOI:10.1016/S0040-4020(01)80767-5

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